Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Prediction of Blast-Induced Rock Movement During Bench Blasting: Use of Gray Wolf Optimizer and Support Vector Regression     

Yu  Zhi  Shi  Xiuzhi  Zhou  Jian  Chen  Xin  Miao  Xiaohu  Teng  Bing  Ipangelwa  Timo 《Natural Resources Research》2020,29(2):843-865

Natural Resources Research - A large ore loss and dilution can be expected when using a pre-blast ore boundary for shovel guidance because of the movement and re-distribution of ore in the muck...  相似文献   

Optical flashes and very early afterglows in wind environments     

X. F. Wu  Z. G. Dai  Y. F. Huang  T. Lu 《Monthly notices of the Royal Astronomical Society》2003,342(4):1131-1138

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宇宙磁场中的中微子     

石最坚  李双九  康文秀  李佩琏 《中国天文和天体物理学报》1990,(4)

本文讨论了有质量的Dirac粒子在宇宙磁场中的演化。宇宙磁场使空间度规出现各向异性。通过求解Dirac方程,得到了中微子在宇宙磁场中的表观磁矩。  相似文献   

An approximate method for evaluating the shear band thickness in saturated soils     

X. B. Lu  Wang Shuyun  Wang Yihua  Peng Cui 《国际地质力学数值与分析法杂志》2004,28(15):1533-1541

A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Observational constraints on the radio and γ-ray emission regions of PSR B1055−52     

H. G. Wang  G. J. Qiao  R. X. Xu  Y. Liu 《Monthly notices of the Royal Astronomical Society》2006,366(3):945-952

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P‐wave transmission across fractures with nonlinear deformational behaviour     

X. B. Zhao  J. Zhao  J. G. Cai 《国际地质力学数值与分析法杂志》2006,30(11):1097-1112

Stress wave attenuation across fractured rock masses is a great concern of underground structure safety. When the wave amplitude is large, fractures experience nonlinear deformation during the wave propagation. This paper presents a study on normal transmission of P‐wave across parallel fractures with nonlinear deformational behaviour (static Barton–Bandis model). The results show that the magnitude of transmission coefficient is a function of incident wave amplitude, nondimensional fracture spacing and number of fractures. Two important indices of nondimensional fracture spacing are identified, and they divide the area of nondimensional fracture spacing into three parts (individual fracture area, transition area and small spacing area). In the different areas, the magnitude of transmission coefficient has different trends with nondimensional fracture spacing and number of fractures. In addition, the study reveals that under some circumstances, the magnitude of transmission coefficient increases with increasing number of fractures, and is larger than 1. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

亚毫米波射电天文用超导SIS接收机的研制(英文)     

史生才 《紫金山天文台台刊》2003,(1)

为了研制亚毫米波射电天文用超导SIS(超导 -绝缘体 -超导 )接收机 ,我们重点开展了如下研究 ,1 )Nb超导SIS结在其能隙频率附近的量子混频特性 ,及其结合高能隙超导薄膜 (NbTiN)和高电导率金属薄膜 (Al)分布结阵在 780 - 950GHz频率区间的量子混频特性 ;2 )亚毫米波超导混频器嵌入阻抗的数值和实验表征 ;3)高电流密度小面积Nb超导SIS结的制备和特性表征 ;4)一个 60 0 - 72 0GHz超导SIS混频器的研制和特性表征。本文详细介绍了相关的数值分析和实验测量结果。  相似文献   

Observational evidence for solar coronal decimetric radio pulsations with very short periods     

Xie Rui-xiang  Wang Min  Shi Shuo-biao  Xu Chun  Li Wei-hua  Yan Yi-hua 《Chinese Astronomy and Astrophysics》2003,27(4):426-434

Using the decimetric (700–1500 MHz) radio spectrometer and the synchronous observational system with high temporal resolution at four frequencies (1420, 2130, 2840 and 4260 MHz) of Yunnan Observatory, two rare events were observed on 2001 June 24 and 1990 July 30. The former was a small radio burst exhibiting pulsations with short periods (about 29, 40 and 100 ms) in the impulsive phase. The latter was a large radio burst, which at 2840 MHz produced radio pulsations with period of about 30 ms. This paper focuses on pulsations with very short periods in the range of 29–40 ms. The mechanism of generation of such pulsations may be modulation of radio radiation by the periodic trains of whistler packets originating in unstable regions of the corona. Alternatively, these pulsations can be attributed to wave-wave non-linear interactions of electrostatic upper hybrid waves driven by beams of precipitating electrons in flaring loops.  相似文献   

On signal–noise decomposition of time-series using the continuous wavelet transform: application to sunspot index     

J. Polygiannakis  P. Preka-Papadema  X. Moussas 《Monthly notices of the Royal Astronomical Society》2003,343(3):725-734

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